Introduction

Solid biofuels are a potential source of renewable energy. One of the major barriers to their widespread use is they have a lower energy content than traditional fossil fuels, which means more fuel is required to get the same amount of energy. When combined — low energy content with low density — the volume of solid biofuels handled increases enormously. Compaction or densification is one way to increase the energy density and overcome handling and storage difficulties, especially for sources of agricultural-based solid biofuels. This fact sheet examines the density properties of solid biofuels and potential densification technologies.

Bulk density

Bulk density is defined as the weight per unit volume of a material, expressed in kilograms per cubic metre (kg/m3) or pounds per cubic foot (lb/ft3). Most agricultural residues have low bulk densities, as shown in Figure 1.

Typical bulk densities of unprocessed solid biofuels and fossil fuels

Figure 1. Typical bulk densities of unprocessed solid biofuels and fossil fuels.

Accessible description of Figure 1

For example, the bulk density of loose wheat straw is approximately 18 kg/m3 (1.1 lb/ft3), in comparison to coal at 700 kg/m3 (44 lb/ft3). For this reason, it is only economically feasible to transport unprocessed solid biofuels less than approximately 200 kmfootnote 1.

Energy density

Energy density is a term used to describe the amount of energy stored per unit volume, often expressed in MJ/m3 or BTU/ft3.

Figure 2 is a graphical representation of common volume ratios for unprocessed material, with the cubes representing the volume of material required for equal energy, 16:4:1 for straw to wood to coal.

Typical bulk densities of unprocessed solid biofuels and fossil fuels

Figure 2. Typical bulk densities of unprocessed solid biofuels and fossil fuels.

Accessible description of Figure 2

Why densify

The low density of solid biofuels poses a challenge for the handling, transportation, storage and combustion processes. These problems may be addressed through densification, a process that produces either liquid or solid biofuel with denser and more uniform properties than the raw biomass.

The main advantages of solid biofuel densification for combustion are:

  • simplified mechanical handling and feeding
  • uniform combustion in boilers
  • reduced dust production
  • reduced possibility of spontaneous combustion in storage
  • simplified storage and handling infrastructure, lowering capital requirements at the combustion plant
  • reduced cost of transportation due to increased energy density

The major disadvantage to solid biofuel densification technologies is the high cost associated with some of the densification processes.

Pre-treatment of solid biofuel

Prior to solid biofuel densification, pre-treatments may be required to optimize the energy content and bulk density of the product.

Pre-treatment can include:

  • chop length/grinding
  • drying to required moisture content
  • application of a binding agent
  • steaming
  • torrefaction

Chop length/grinding

Each densification process requires specific chop length and/or grinding to achieve:

  • lower energy use in the densification process
  • denser products
  • a decrease in breakage of the outcome productfootnote 2

Drying

Low moisture results in improved density and durability of the biofuelfootnote 3. For most solid biofuel densification processes, the optimum moisture content is in the range of 8–20% (wet basis)footnote 4. Most compaction techniques require a small amount of moisture (such as steam) to “soften” the biomass for compaction. Above the optimum moisture level, the strength and durability of the densified solid biofuel are decreased.

Addition of a binding agent

The density and durability of densified solid biofuel are influenced by the natural binding agents of the material. The binding capacity increases with a higher protein and starch contentfootnote 5. Corn stalks have high binding properties, while warm-season grasses, which are low in protein and starch content, have lower binding propertiesfootnote 6. Binding agents may be added to the material to increase binding properties. Commonly used binders include vegetable oil, clay, starch, cooking oil or wax.

Steaming

The addition of steam prior to densification can aid in the release and activation of natural binders present in the solid biofuel, such as lignin.

Torrefaction

Torrefaction is a version of pyrolysis processes that involve the heating of solid biofuel in the absence of oxygen and air. Torrefaction is a pre-treatment process used to improve the properties of pellets. It can also be used as a stand-alone technique to improve the properties of solid biofuel. Torrefaction is a mild version of slow pyrolysis where the goal is to dry, embrittle and waterproof the solid biofuel. This is accomplished by heating the solid biofuel in an inert environment at temperatures of 280–320°C.

Techniques for solid biofuel densification

Solid biofuel is densified via 2 main processes: mechanical densification and pyrolysis. Mechanical densification involves applying pressure to mechanically densify the material. Pyrolysis involves heating the solid biofuel in the absence of oxygen. In general, lower temperatures at longer processing times (such as slow pyrolysis) favour solid (charcoal) production. Medium temperatures (400–500°C) at very short times (1–2 seconds), known as fast pyrolysis, favour liquid biofuel or bio-oil production.

The method of densification depends on the type of residues and the local situation. The various technologies are used to increase the solid biofuel energy density and/or mould the fuel into a homogeneous size and shape.

two round bales of hay in a field

Mechanical densification — bales are a traditional method of densification commonly used to harvest crops. A bale is formed using farm machinery (called a baler) that compresses the chop. Bales can be square, rectangular or round, depending on the type of baler used. The dimensions of round bales range from 1.2 m × 1.5 m (4 ft × 5 ft) to 1.5 m × 1.5 m (5 ft  × 5 ft). Large rectangular bales typically measure 0.9 m × 0.9 m × 1.8 m (3 ft × 3 ft × 6 ft) in length. Round bales are less expensive to produce, however, large square bales are usually denser and easier to handle and transport.

small pile of pellets

Source: CanmetENERGY.

Mechanical densification — pellets are very high in density. They are easier to handle than other densified solid biofuel products, since infrastructure for grain handling is used for pellets. Pellets are formed by an extrusion process, using a piston press, where finely ground solid biofuel material is forced through round or square cross-sectional dies and cut to a desired length. The standard shape of a solid biofuel pellet is a cylinder, having a length smaller than 38 mm (1.5 in.) and a diameter around 7 mm (0.3 in.). Although uniform in shape, pellets are easily broken during handling. Different grades of pellets vary in energy and ash content.

small pile of square shaped cubes of biomass

Source: CanmetENERGY.

Mechanical densification — cubes are larger pellets, usually square in shape. Cubes are less dense than pellets. Cube sizes range from 13–38 mm (0.5–1.5 in.) in cross section, with a length ranging 25–102 mm (1–4 in.). The process involves compressing chopped solid biofuel with a heavy press wheel, followed by forcing the solid biofuel through dies to produce cubes.

briquette of biomass

Source: Wayne Winkler.

Mechanical densification — briquettes are similar to pellets but differ in size. Briquettes have a diameter of 25 mm (1 in.) or greater and are formed when solid biofuel is punched, using a piston press, into a die under high pressure. Alternatively, a process referred to as screw extrusion can be used. In screw extrusion, the solid biofuel is extruded by a screw through a heated die. Solid biofuel densified through screw extrusion has higher storability and energy density properties compared to solid biofuel produced by piston press.

4 round biomass pucks stacked on each other

Mechanical densification — pucks are similar in appearance to a hockey puck, with a 75 mm (3 in.) diameter. They are produced using a briquetter and are resilient to moisture. Pucks have a similar density as pellets, with the advantage that they require lower production costs compared to pelletization.

wood chips

Source: CanmetENERGY.

Mechanical densification — wood chips are used in many operations, from household appliances to large-scale power plants. Woodchips for boilers range in size, 5–50 mm (0.2–2 in.) in length. Woodchips are made with a woodchipper. In terms of fuel, woodchips are comparable in cost to coal.

pile of biomass pellets created through torrefaction

Source: CanmetENERGY.

Pyrolysis — torrefaction is carried out by heating solid biofuel in an inert atmosphere at temperatures of 280–320°C for a few minutes. The torrefied fuel shows improved grindability properties. Torrefied solid biofuel has hydrophobic properties (repels water), making it resistant to biological attack and moisture, thereby facilitating its storage. The process requires little energy input since some of the volatile gases liberated during heating are combusted, generating 80% of the heat required for torrefaction. Torrefied solid biofuel is densified into pellets or briquettes, further increasing the density of the material and improving its hydrophobic properties.

charcoal that has been created using slow pyrolysis

Source: CanmetENERGY.

Pyrolysis — slow pyrolysis involves heating biomass to 350–500°C in the absence of oxygen and air for extended periods of time (typically 0.5–2 hours). The principal product is a solid (charcoal) that retains 30–40% of the original energy from the raw solid biofuel. The energy density can be increased, and thus charcoal is a suitable fuel for commercial uses similar to torrified solid biofuel, residential use, such as barbecues, and as a potential soil improvement additive known as bio-char.

lab technician pouring a bio-oil from one beaker to another

Source: CanmetENERGY.

Pyrolysis — fast pyrolysis involves processing solid biofuel at temperatures of up to 450–500°C for 1–2 seconds. The process yields up to 75% bio-oil and 10–15% charcoal. Bio-oil is a higher-energy density fuel, and its handling properties are simplified, as the fuel is a liquid that is pumped and stored in tanks. Precautions are necessary, as bio-oils are very acidic, have a pungent odour and are prone to separation/settling. Substitute bio-oil for fossil fuel, heavy and middle oils. Research is under way to explore conversion to lighter oils such as diesel and gasoline.

Conversion

FromToMultiply by
mminch0.0394
inchft0.0833
kg/m3lb/ft30.0624
MJ/kgBTU/lb430

Through various densification technologies, raw solid biofuel is compressed to densities in the order of 7–10 times its original bulk densityfootnote 7. The bulk densities for selected pre-processing technologies are displayed in Table 1, as well as in Figure 3.

Table 1. Density of solid biofuel for selected densification technologies
Form of solid biofuelShape and size characteristicsDensity (lb/ft3)Density (kg/m3)Energy density (GJ/m3)
Traditional method 
Baled agricultural residues

Large round, Soft core

1.2 × 1.2, 1.2 × 1.5, 1.5 × 1.2, 1.8 × 1.5 m

(4 × 4, 4 × 5, 5 × 4, 6 × 5 ft) diameter × width

10–12160–1902.8–3.4
Traditional method 
Baled agricultural residues

Large round, Hard core

1.2 × 1.2, 1.2 × 1.5, 1.5 × 1.2, 1.8 × 1.5 m

(4 × 4, 4 × 5, 5 × 4, 6 × 5 ft) diameter × width

12–15190–2403.4–4.5
Traditional method 
Baled agricultural residues

Large/Mid-size square

0.6 × 0.9 × 2.4 m (2 × 3 × 8 ft)

0.9 × 1.2 × 2.4 m (3 × 4 × 8 ft)

13–16210–2553.7–4.7
Non-traditional method 
Ground forestry residuesfootnote 8 (such as hammermill)
1.5 mm (0.06 in.) pack fill with tapping132003.6
Non-traditional method 
Briquettesfootnote 8
32 mm (1.3 in.) diameter × 25 mm (1 in.) thick223506.4
Non-traditional method 
Cubesfootnote 8
33 mm (1.3 in.) × 33 mm (1.3 in.) cross section254007.3
Non-traditional method 
Pucksfootnote 9
75 mm (3 in.) diameter × 12 mm (0.5 in.) thick30–40480–6408.6–12.0
Non-traditional method 
Pelletsfootnote 8
6.24 mm (0.2 in.) diameter35–45550–7009.8–14.0
Non-traditional method 
orrefied pelletsfootnote 10
6.24 mm (0.2 in.) diameter5080015.0
Non-traditional method 
Bio-oilfootnote 10
liquid751,20020

Note: Loose solid biofuel has a density of 3.5–5 lb/ft3 or 60–80 kg/m3.

Resulting bulk densities of solid biofuel for selected densification technologies

Figure 3. Resulting bulk densities of solid biofuel for selected densification technologies.

Accessible description of Figure 3

Solid biofuel densification cost

Pyrolyzed materials are the most expensive to densify, with cubes, pucks, briquettes and woodchips being less expensive.

Factors affecting the cost of densification technologies includefootnote 11:

  • size of densification plant (tonnes/year)
  • operating time (hours/day)
  • equipment cost
  • personnel cost
  • raw material costs

Densification technologies result in higher energy inputs and increased costs. A portion of the cost is recuperated by the lower handling, storage and transportation costs, and better operability of the boiler and combustion process. Some densification technologies mentioned are commercially available, while others are emerging.

Conclusion

The low-energy density of solid biofuel by volume, in comparison with fossil fuels, results in higher handling, storage and transportation costs. Consequently, solid biofuel is most economically feasible when used close to the source. The cost of transportation is reduced through densification technologies. Densification technologies produce a homogeneous product with a higher energy density than that of the original raw material, at the expense of new capital and operating costs.

Author credits

This fact sheet was updated by Terrence Sauvé, P. Eng., farmstead optimization and safety engineer, Ministry of Agriculture, Food and Agribusiness (OMAFA). It was originally written by Steve Clarke, P. Eng., engineer, energy and crop engineering specialist, OMAFA, Kemptville, and Fernando Preto, Bioenergy Systems, CanmetENERGY.

Accessible image descriptions

Figure 1. Typical bulk densities of unprocessed solid biofuels and fossil fuels.

Figure 1 is a bar chart comparing the bulk density of several biomass materials in pounds per cubic foot and kilograms per cubic metre. Materials shown from left to right are: wheat straw, corn stover, soybean hulls, oat hulls, corn cobs, hardwood, and lignite coal. The bars increase in height across the chart, with lignite coal having the highest density (around 700 kilograms per cubic metre) and wheat straw the lowest. Source citations are listed below the chart.

Figure 2. Typical bulk densities of unprocessed solid biofuels and fossil fuels.

Figure 2 is a drawing of three boxes side by side. The largest box has the word straw written across the centre, followed by a smaller middle box with the word wood written across the centre and a small box with the word coal written across the centre. The diagram shows the equivalent energy content by volume of unprocessed materials.

Figure 3. Resulting bulk densities of solid biofuel for selected densification technologies.

Figure 3 is a bar chart comparing the bulk density of various biomass densification technologies in pounds per cubic foot and kilograms per cubic metre. Categories shown from left to right are: ground biomass, large round bale, large square bale, briquettes, cubes, wafers, pellets, torrefied pellets, bio‑oil, and lignite coal. Bulk density increases across the chart, with lignite coal having the highest density (over 1,000 kilograms per cubic metre).