Attachments
Attachment 1: Reference Source Testing Methods
This Attachment contains a list of acceptable methods for the measurement of emissions of air pollutants from stationary sources when such emission data are required for the purpose of determining compliance with the Environmental Protection Act of the Province of Ontario and the regulations thereunder.
These methods comprise the most up-to-date procedures available at the date of issue of this Code; however, as new and improved techniques become available, the most current version of the methods shall be used when conducting source testing.
The stack gas parameters determination are covered in detail in Parts B to E (Methods ON-1 to ON-4) of this code, and are commonly used for each stack gas test. However, these four methods are often performed simultaneously when using Method ON-5 or modified Method ON-5 sampling trains.
For contaminants without established reference test methods the proponent should demonstrate to the satisfaction of the Source Assessment Specialist that the stack gas sampling, sample recovery and analysis accurately represent what is being discharged to the atmosphere.
1. List of Reference Source Testing Assessment Methods for Contaminants Listed in O.Reg. 419/05
Item | CAS No. | Contaminant | Reference Method (Source Testing) |
---|---|---|---|
1. | 75-07-0 | Acetaldehyde | CARB Method 430 |
2. | 64-19-7 | Acetic Acid | NIOSH Method 1603 - Modified |
3. | 67-64-1 | Acetone | US EPA SW-846 Method 0030 |
4. | 74-86-2 | Acetylene | OSHA Chemical Sampling Information |
5. | 79-06-1 | Acrylamide | OSHA Method 21 - Modified |
6. | 107-13-1 | Acrylonitrile | US EPA SOP# 1704 |
7. | 7664-41-7 | Ammonia | US EPA Method CTM-027 |
8. | 7440-36-0 | Antimony | US EPA 40CFR60 Method 29 |
9. | 7784-42-1 | Arsine | NIOSH Method 6001 - Modified |
10. | 7440-41-7 | Beryllium and compounds | US EPA 40CFR60 Method 29 |
11. | 7440-42-8 | Boron | US EPA 40CFR60 Method 29 |
12. | 10294-33-4 | Boron Tribromide | OSHA CSI Method – Modified |
13. | 10294-34-5 | Boron Trichloride | US EPA 40CFR60 Method 29, or US EPA 40CFR60 Method 26 |
14. | 7637-07-2 | Boron Trifluoride | OSHA CSI Method – Modified |
15. | 7726-95-6 | Bromine | US EPA 40CFR60 Method 26 |
16. | 7440-43-9 | Cadmium | US EPA 40CFR60 Method 29 |
17. | 1305-62-0 | Calcium Hydroxide | US EPA 40CFR60 Method 29 |
18. | 1305-78-8 | Calcium Oxide | US EPA 40CFR60 Method 29 |
19. | 1333-86-4 | Carbon Black | OSTC Method ON-5 |
20. | 75-15-0 | Carbon Disulphide | Environment Canada Method EPS 1/RM/6 |
21. | 630-08-0 | Carbon Monoxide | US EPA 40CFR60 Method 10 |
22. | 56-23-5 | Carbon Tetrachloride | US EPA SW-846 Method 0030 |
23. | 7782-50-5 | Chlorine | US EPA 40CFR60 Method 26 |
24. | 10049-04-4 | Chlorine Dioxide | NCASI Technical Bulletin 520 |
25. | 67-66-3 | Chloroform | US EPA SW-846 Method 0030 |
26. | - | Chromium - Speciation | US EPA SW846 Method 0061 |
27. | 7440-47-3 | Chromium – Total | US EPA 40 CFR 60 Method 29 |
28. | 7440-50-8 | Copper | US EPA 40CFR60 Method 29 |
29. | 1319-77-3 | Cresols | NIOSH Method 2546 - Modified |
30. | 17702-41-9 | Decaborane | OSHA CSI Method – Modified |
31. | 117-81-7 | Di(2-ethylhexyl) Phthalate | NIOSH Method 5020 – Modified |
32. | 19287-45-7 | Diborane | NIOSH Method 6006 – Modified |
33. | 131-15-7 | Dicapryl Phthalate | OSHA Method 104 – Modified |
34. | 106-46-7 | Dichlorobenzene, 1,4- | Environment Canada Method EPS 1/RM/2 |
35. | 624-92-0 | Dimethyl Disulphide | Environment Canada Method EPS 1/RM/6 |
36. | 75-18-3 | Dimethyl Sulphide | Environment Canada Method EPS 1/RM/61/RM/6 |
37. | 117-84-0 | Di-n-Octyl Phthalate | OSHA Method 104 – Modified |
38. | - | Dustfall | ASTM Method D1739-98 (2004) |
39. | 141-78-6 | Ethyl Acetate | US EPA 40CFR60 Method 18 -Tedlar® Bag - GC-FID |
40. | 140-88-5 | Ethyl Acrylate | NIOSH Method 1450 - Modified |
41. | 100-41-4 | Ethyl Benzene | US EPA SW-846 Method 0030 |
42. | 60-29-7 | Ethyl Ether | NIOSH Method 1610 - Modified |
43. | 107-06-2 | Ethylene Dichloride | US EPA SW-846 Method 0030 |
44. | 1309-37-1 | Ferric Oxide | US EPA 40CFR 60 Method 29 |
45. | 7664-39-3 | Fluorides (as HF) - Gaseous (Growing Season) | US EPA 40CFR60 Method 13B |
46. | 7664-39-3 | Fluorides (as HF) - Total (Growing Season) | US EPA 40CFR60 Method 13B |
47. | 7664-39-3 | Fluorides (as HF) - Total (Non-Growing Season) | US EPA 40CFR60 Method 13B |
48. | 50-00-0 | Formaldehyde | CARB Method 430 |
49. | 64-18-6 | Formic Acid | NIOSH Method 2011 - Modified |
50. | 98-01-1 | Furfural | NIOSH Method 2529 - Modified |
51. | 98-00-0 | Furfuryl Alcohol | NIOSH method 2505 - Modified |
52. | 7647-01-0 | Hydrogen Chloride | US EPA 40CFR60 Method 26/26A |
53. | 7783-06-04 | Hydrogen Sulphide | US EPA 40CFR60 Method 11 |
54. | 15438-31-0 | Iron (metallic) | US EPA 40CFR60 Method 29 |
55. | - | Isocyanates Speciation | US EPA CTM-036 |
56. | 98-82-8 | Isopropyl Benzene (cumene) | US EPA SW-846 Method 0030 |
57. | 7439-92-1 | Lead | US EPA 40CFR60 Method 29 |
58. | 7439-93-2 | Lithium | US EPA 40CFR60 Method 29 |
59. | 7580-67-8 | Lithium Hydrides | US EPA 40CFR60 Method 29 |
60. | 1309-48-4 | Magnesium Oxide | US EPA 40CFR60 Method 29 |
61. | 74-93-1 | Mercaptans | Environment Canada Method EPS 1/RM/6 |
62. | 7439-97-6 | Mercury (Hg) | US EPA 40CFR60 Method 29 |
63. | 7439-97-6 | Mercury (Hg) | US EPA 40CFR60 Method 30B |
64. | 7439-97-6 | Mercury (as Hg) – alkyl compounds | US EPA 40CFR60 Method 101 |
65. | 67-56-1 | Methanol (Methyl Alcohol) | US EPA 40CFR60 Method 308 |
66. | 96-33-3 | Methyl Acrylate | NIOSH Method 2537 - Modified |
67. | 71-55-6 | Methyl Chloroform (1,1,1- Trichloroethane) | US EPA SW-846 Method 0030 |
68. | 78-93-3 | Methyl Ethyl Ketone (2- Butanone) | US EPA SW-846 Method 0030 |
69. | 108-10-1 | Methyl Isobutyl Ketone | US EPA SW-846 Method 0030 |
70. | 80-62-6 | Methyl Methacrylate | NIOSH Method 2537 - Modified |
71. | - | Milk Powder | OSTC Method ON-5 |
72. | - | Mineral Spirits (Naphthas) | NIOSH Method 1550 - Modified |
73. | 74-89-5 | Monomethyl Amine | OSHA Method 40 – Modified |
74. | 142-82-5 | n-Heptane | US EPA SW-846 Method 0030 |
75. | 7440-02-0 | Nickel | US EPA 40CFR60 Method 29 |
76. | 13463-39-3 | Nickel Carbonyl | NIOSH Method 6007 - Modified |
77. | 7697-37-2 | Nitric Acid | US EPA Method CTM027 – Modified |
78. | 139-13-9 | Nitrilotriacetic Acid | BC Laboratory Methods Manual |
79. | 10102-44-0 | Nitrogen Oxides | US EPA 40CFR60 Method 7E |
80. | 10028-15-6 | Ozone | OSHA Method 214 – Modified |
81. | 19624-22-7 | Pentaborane | OSHA CSI Method - Modified |
82. | 108-95-2 | Phenol | US EPA 40CFR60 Method 318 |
83. | 75-44-5 | Phosgene | US EPA Draft Method |
84. | 7664-38-2 | Phosphoric Acids | CARB Method 421 |
85. | 85-44-9 | Phthalic Anhydride | OSHA Method 90 – Modified |
86. | 78-87-5 | Propylene Dichloride | NIOSH Method 1013 - Modified |
87. | 75-56-9 | Propylene Oxide | NIOSH Method 1612 - Modified |
88. | 7440-22-4 | Silver | US EPA 40CFR60 Method 29 |
89. | 100-42-5 | Styrene | US EPA SW-846 Method 0030 |
90. | 7446-09-5 | Sulphur Dioxide | US EPA 40CFR60 Method 6C |
91. | 7664-93-9 | Sulphuric Acid | US EPA 40CFR60 Method 8 |
92. | - | Suspended Particulate Matter (< 44 µm Diameter) | OSTC Method ON-5 |
93. | 13494-80-9 | Tellurium (except hydrogen telluride) | US EPA 40CFR60 Method 29 |
94. | 109-99-9 | Tetrahydrofuran | NIOSH Method 1609 - Modified |
95. | 7440-31-5 | Tin | US EPA 40CFR60 Method 29 |
96. | 7440-32-6 | Titanium | US EPA 40CFR60 Method 29 |
97. | 108-88-3 | Toluene | US EPA SW-846 Method 0030 |
98. | 584-84-9 | Toluene Di-isocyanate, 2,4- | US EPA CTM-036 |
99. | 79-01-6 | Trichloroethylene (TCE) | US EPA SW-846 Method 0030 |
100. | 76-13-1 | Trifluorotrichloroethane | US EPA SW-846 Method 0030 |
101. | 7440-62-2 | Vanadium | US EPA 40CFR60 Method 29 |
102. | 75-01-4 | Vinyl Chloride | US EPA 40CFR60 Method 106 |
103. | 75-35-4 | Vinylidene Chloride (1,1-Dichloroethene) | US EPA SW-846 Method 0030 |
104. | 1330-20-7 | Xylenes | US EPA SW-846 Method 0030 |
105. | 7440-66-6 | Zinc | US EPA 40CFR60 Method 29 |
O. Reg. 419/05; O. Reg. 605/05.
- ASTM
- The American Society for Testing and Materials
- BC
- British Columbia
- CARB
- State of California Air Resources Board
- CSI
- OSHA Chemical Sampling Information
- NIOSH
- US National Institute for Occupational Safety and Health
- OSHA
- US Occupational Safety & Health Administration
- OSTC
- Ontario Source Testing Code
- SOP
- Standard Operating Procedure
- US EPA
- United States Environmental Protection Agency
2. List of Reference Source Testing Assessment Methods for Contaminants Not Listed in O. Reg. 419/05
Item | Contaminant | Reference Method (Source Testing) |
---|---|---|
1. | Aldehydes | CARB Method 430 |
2. | Acetic Acid | NIOSH Method 1603 - Modified |
3. | Acetone | US EPA SW-846 Method 0030 |
4. | Asbestos | CARB Method 427, or Environment Canada Method EPS 1-AP-75-1 |
5. | Benzene | CARB Methods 410A/410B |
6. | Carbon Dioxide | US EPA 40 CFR60 Method 3A |
7. | Carbon Disulphide | US EPA 40 CFR60 Method 15 |
8. | Carbon Monoxide | US EPA 40 CFR60 Method 10 |
9. | Carbonyl Sulphide | Environment Canada Method EPS 1/RM/2 |
10. | Chlorobenzene | Environment Canada Method EPS 1/RM/2 |
11. | Chlorophenol | Environment Canada Method EPS 1/RM/2 |
12. | Chromium Speciation | US EPA SW846 Method 0061 |
13. | Chromium - Total | US EPA 40 CFR60 Method 29 |
14. | Cyanide | CARB Method 426 |
15. | Dioxins | Environment Canada Method EPS 1/RM/2 |
16. | Ethylene Oxide | CARB Method 431 |
17. | Furans | Environment Canada Method EPS 1/RM/2 |
18. | Hydrogen Halides | US EPA 40CFR60 Methods 26/26A |
19. | Hydrogen Sulphide | US EPA 40CFR60 Method 11 |
20. | Isocyanates Speciation | US EPA CTM-036 |
21. | Metals | US EPA 40CFR60 Method 29 |
22. | Mercury Speciation | ASTM Method D6784-02 |
23. | Microbial Survivability Test for Medical Waste Incinerator Emissions | US EPA Method CTM-026 |
24. | Odour | OSTC Method ON-6 |
25. | Opacity | US EPA 40CFR60 Method 9 |
26. | Orthophosphate | Alberta Method 45050/45051 |
27. | Oxygen | US EPA Methods 3A |
28. | PM10 | US EPA 40CFR60 Method 201A |
29. | PM10/PM2.5 | US EPA Method CTM-040 |
30. | Particulate Matter (Condensable) | US EPA 40CFR60 Method 202 |
31. | Polonium 210 | US EPA 40CFR60 Method 111 |
32. | Polychlorinated Dibenzo-p-Dioxins | Environment Canada Method EPS 1/RM/2 |
33. | Polychlorinated Dibenzo Furans | Environment Canada Method EPS 1/RM/2 |
34. | Polychlorinated Biphenyls (PCBs) | Environment Canada Method EPS 1/RM/2 |
35. | Polynuclear Aromatic Hydrocarbons | Environment Canada Method EPS 1/RM/2 |
36. | Total Gaseous Non-methane Organics | US EPA Method 25 |
37. | Total Gaseous Organics | US EPA Method 25A |
38. | Total Reduced Sulphur (TRS) – Non-Speciated | US EPA Method |
38. | Total Reduced Sulphur (TRS) - Speciated | Environment Canada Method EPS 1/RM/6 |
39. | Urea | Alberta Method 47575 |
40. | Volatile Organic Constituents |
US EPA SW-846 Method 0030 |
- Alberta
- Alberta Environment (Canada)
- CARB
- State of California Air Resources Board
- US EPA
- United States Environmental Protection Agency
- OSTC
- Ontario Source Testing Code
Attachment 2: Guidebook to Prepare a Pre-Test Plan Document
Acknowledgement
This document is based on the U.S. Environmental Protection Agency’s “Guidebook on the Preparation and Review of Site-Specific Test Plans”. It has been adapted to reflect requirements specific to Ontario, e.g., references to Certificates of Approval.
Purpose And Use Of Guidebook
The purpose of this guidebook is to provide a standard format for preparing pre-test plans for compliance source test programs such as those required by Certificates of Approval, Provincial Officers’ Orders and notices issued by the Ontario Ministry of Environment.
The same guidebook format should be used for source test programs if the results are intended to be accepted as representative and accurate by the Ministry. Any tests done for these reasons and to this level of Quality Assurance/Quality Control (QA/QC) are referred to as being of “compliance quality.”
A properly prepared pre-test plan should include written descriptions, summary tables, and figures that encompass all aspects in the planning of an emissions test program. The pre-test plan is to provide the information necessary to determine whether a testing organization understands the objectives of the test and whether the test includes appropriate procedures to accomplish these objectives.
The pre-test plan guidebook has been developed to facilitate the preparation of pre-test plans by outlining the information required. Following this guidebook will make the preparation of the pre-test plan easier and more effective.
Summary Of Source Testing Procedure
- A compliance test is a source test conducted for the purpose of determining compliance with the Environmental Protection Act of Ontario or the regulations promulgated thereunder, performed and reported in accordance with the requirements of Part A of this code. The Ministry must be advised of any proposed compliance testing prior to testing and supplied with a term of reference which should include at least relevant process and test information. If required, a Ministry official must be allowed to tour the process, inspect the sampling site and witness the sampling tests. It must be demonstrated that the testing was performed at process conditions effecting the maximum pollutant emissions, e.g., at normal maximum production rates excluding process upsets, and that the test results truly represent the emissions from this source. A complete final report must be submitted to the Ministry.
- Three replicate samples must be taken over a sufficient time to represent the source accurately. Refer to this Code’s Parts A through F for specific requirements.
- Under the Ministry’s normal practice, compliance source testing may be witnessed by the Ministry, if deemed necessary.
- Following the Ministry’s approval of the pre-test plan, the Company shall notify the Ministry in writing of the location, date and time of any impending Source Testing required for compliance, at least fifteen (15) days prior to the Source Testing.
- In order to avoid unnecessary and unproductive time of witnessing staff on-site, it is important to keep this Ministry informed of any changes or delays in starting times for source tests. While downtime of equipment may be unforeseeable in some cases, an effort to minimize this during the time our staff is on-site would be greatly appreciated. The appropriate regional office should be contacted to obtain the appropriate telephone number of Ministry staff looking after that specific plant or geographical area where the plant under study is located.
- The emission test report resulting from the source testing should be submitted to the Ministry.
Download Guidebook to Prepare a Pre-Test Plan Document
Attachment 3:Recommended Qualifications for Stack Sampling Team
It is essential for the production of valid test data that the emissions measurement program be performed by qualified personnel using proper test equipment.
The source sampling team should consist of no less than two persons to perform the tests at the sampling site. A third person should be included when sampling variable rate processes, to correlate the sampling activity with the manufacturing process. For multi-stack sampling, the team should be increased accordingly.
One of the two persons shall be the source testing supervisor or leader, who will ensure that sampling is conducted properly and that the process is operating at the maximum or required production rate.
The source testing supervisor or leader must have sufficient experience and understanding of industrial processes and source testing to perform activities outlined in the introduction. The supervisor or leader must have an educational background in engineering, engineering technology or environmental science, or at least two (2) years of source testing field experience conducting source testing.
The remaining members of the source testing team should have sufficient experience to prepare and operate source sampling trains in a competent manner. He or she should have successfully completed in-house or external training on source testing and have previous field experience in source testing using the reference methods mentioned in this code.
Other stack testing team members with no previous experience in source testing must have successfully completed an in-house or external training on source testing, followed by at least two week period of source testing field observation. ASTM D7036 can be used as a general guide on determining personnel competency to carry out sampling and analysis of stationary source testing programs.
References
- Ministry of the Environment, Province of Ontario, Source Testing Code, Version 2, November 1980.
- United States Environmental Protection Agency, Preparation and Review of Site-Specific Test Plans, December 1991.
Footnotes
- footnote[1] Back to paragraph This method must be used in conjunction with Environment Canada’s Method 1/RM/3 and the Methodology for Organic Analysis - NITEP/Mid-Connecticut Combustion Test.
- footnote[2] Back to paragraph This method must be used in conjunction with Environment Canada’s Method 1/RM/3 and Report EPS 1/RM/23.
- footnote[3] Back to paragraph This method must be used in conjunction with Environment Canada’s Methodology for Organic Analysis - NITEP/Mid-Connecticut Combustion Test.
- footnote[4] Back to paragraph Refer to the reference method for a list of constituents that can be sampled with this method.